Sterically-hindered Organosilicon Compounds Containing Cyclohexyl Groups. III. Notes on Petrov and Chernysheva’s Tetracyclohexylsilane and Tricyclohexyl-n-butylsilane
نویسندگان
چکیده
منابع مشابه
Some highly sterically hindered organosilicon compounds
The chemistry of organometallic compounds with bulky ligands such as (Me3Si)3C(Tsi) or (Me2PhSI)3C(Tpsi) attached to a variety of metal centres is reviewed. The compounds Tsi2M (M = Zn, Cd, Hg) and the rare two co-ordinate TsiMn show exceptional thermal and hydrolytic stability. The corresponding alkylmetal halides form ring or cage structures. In a range of new boron compounds the structures o...
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A series of sterically hindered μ-oxo bis [tricyclohexylantimony (V)] carboxylates [(cyclo-C6H11)3Sb-O-Sb(cycloC6H11)3](OCOR)2 where -OCOR = p-trifluoromethyl mandelate, p-methoxy mandelate, salicyclate, 2pyrazine carboxylate, mandelate has been synthesised and characterised by solid state infrared, H , Fand C NMR spectroscopy, molecular weight and conductance measurements. The newly synthesize...
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The antifertility activity of organoantimony(III) complexes PhSb[RC(NC(6)H(4)S)CH(2)(NC(6)H(4)S)CR'] {R' = CH(3) (R(1)) and R = R' = CF(3) (R(2))} derived from corresponding sterically hinlered bifuinctional tetradentate ligands in the male rats was determined. The administration of compounds R(1) and R(2) at the dose level of 20 mg/kg. b. wt. siignificantly reduced the weights of testes and ep...
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Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, D-7400 Tübingen Z. Naturforsch. 37b, 1623-1632 (1982); received October 19, 1982 X-ray, Steric Hindrance, C14-Tracer Technique, Triarylmethyl Radical, Diazomethane The structure of the title compound 3, C39H32, obtained for the first time by Schlenk and Bornhardt (1912) from triphenylmethyl (1) and diazomethane (2...
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The title compound, C(13)H(19)NO(2)S, was synthesized by the reaction of N-cyclo-hexyl-amine-benzene-sulfonamide and methyl iodide. The crystal packing is stabilized by weak inter-molecular C-H⋯O hydrogen bonds.
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1963
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.36.287